Ishida, T. Sci Rep 14, 2086 (2024). https://doi.org/10.1038/s41598-024-52475-9
You can think of our atmosphere as a big chemistry set, a global churn of gaseous molecules and particles that constantly bounce off and change each other in complicated ways. While the particles are very small, often less than 1% of the thickness of human hair, they have outsized impacts. For example, particles are the seeds of cloud droplets, and the abundance of the particles changes the reflectivity and the amount of clouds, rainfall and climate.
There are biological underpinnings to aging—and so researchers are investigating cell manipulations, transfusions of young blood, and chemical compounds that can mimic low-calorie diets.
Scientists have taken a significant step towards the development of tailor-made chiral nanocarriers with controllable release properties. These nanocarriers, inspired by nature’s helical molecules like DNA and proteins, hold immense potential for targeted drug delivery and other biomedical applications.
The study, led by Professors Emilio Quiñoá and Félix Freire at the Center for Research in Biological Chemistry and Molecular Materials (CiQUS), highlights the intricate relationship between the structure of helical polymers and their self-assembly into nanospheres. By carefully designing the secondary chain, the researchers were able to modulate the acidity of the polymers, influencing their aggregation patterns and leading to the formation of nanoespheres with varying densities.
Intriguingly, the size of these nanospheres could be precisely controlled by simply adjusting the water-to-solvent ratio during their preparation, eliminating the need for stabilizers. This eco-friendly approach paves the way for sustainable synthesis of these particles.
In the decade since their discovery at Drexel University, the family of two-dimensional materials called MXenes has shown a great deal of promise for applications ranging from water desalination and energy storage to electromagnetic shielding and telecommunications, among others. While researchers have long speculated about the genesis of their versatility, a recent study led by Drexel and the University of California, Los Angeles, has provided the first clear look at the surface chemical structure foundational to MXenes’ capabilities.
Using advanced imaging techniques, known as scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS), the team, which also includes researchers from California State University Northridge, and Lawrence Berkeley National Laboratory, mapped the electrochemical surface topography of the titanium carbide MXene — the most-studied and widely used member of the family.
Their findings, published in the 5th anniversary issue of the Cell Press journal Matter (“Atomic-scale investigations of Ti 3 C 2 Tx MXene surfaces”), will help to explain the range of properties exhibited by members of the MXene family and allow researchers to tailor new materials for specific applications.
A research team led by Osaka University discovered that the new organic molecule thienyl diketone shows high-efficiency phosphorescence. It achieved phosphorescence that is more than ten times faster than traditional materials, allowing the team to elucidate this mechanism.
The paper is published in the journal Chemical Science.
Phosphorescence is a valuable optical function used in applications such as organic EL displays (OLEDs) and cancer diagnostics. Until now, achieving high-efficiency phosphorescence without using rare metals such as iridium and platinum has been a significant challenge. Phosphorescence, which occurs when a molecule transitions from a high-energy state to a low-energy state, often competes with non-radiative processes where the molecule loses energy as heat.
Awarded the 2023 Nobel Prize in Chemistry, quantum dots have a wide variety of applications ranging from displays and LED lights to chemical reaction catalysis and bioimaging. These semiconductor nanocrystals are so small – on the order of nanometers – that their properties, such as color, are size dependent, and they start to exhibit quantum properties. This technology has been really well developed, but only in the visible spectrum, leaving untapped opportunities for technologies in both the ultraviolet and infrared regions of the electromagnetic spectrum.
In new research published in Nature Synthesis (“Interdiffusion-enhanced cation exchange for HgSe and HgCdSe nanocrystals with infrared bandgaps”), University of Illinois at Urbana-Champaign bioengineering professor Andrew Smith and postdoctoral researcher Wonseok Lee have developed mercury selenide (HgSe) and mercury cadmium selenide (HgCdSe) nanocrystals that absorb and emit in the infrared, made from already well-developed, visible spectrum cadmium selenide (CdSe) precursors. The new nanocrystal products retained the desired properties of the parent CdSe nanocrystals, including size, shape and uniformity.
“This is the first example of infrared quantum dots that are at the same level of quality as the ones that are in the visible spectrum,” Smith says.
This Perspective explores the potential of organic electrochemical neurons, which are based on organic electrochemical transistors, in the development of adaptable and biointegrable neuromorphic event-based sensing applications.
Eexxeccellent.
Human brains outperform computers in many forms of processing and are far more energy efficient. What if we could harness their power in a new form of biological computing?
A new way to store carbon captured from the atmosphere, developed by researchers at The University of Texas at Austin, works much faster than current methods without the harmful chemical accelerants they require.
In new research published in ACS Sustainable Chemistry & Engineering, the team developed a technique for ultrafast formation of carbon dioxide hydrates. These unique ice-like materials can bury carbon dioxide in the ocean, preventing it from being released into the atmosphere.
“We’re staring at a huge challenge—finding a way to safely remove gigatons of carbon from our atmosphere—and hydrates offer a universal solution for carbon storage. For them to be a major piece of the carbon storage pie, we need the technology to grow them rapidly and at scale,” said Vaibhav Bahadur, a professor in the Walker Department of Mechanical Engineering who led the research. “We’ve shown that we can quickly grow hydrates without using any chemicals that offset the environmental benefits of carbon capture.”
